Anyone watch the pilot yet? You can watch it from amazon for free now until the 23rd here.
What its about:
Chuck Bartowski (Zachary Levi) is a computer geek that gets catapulted into a new career as the government's most vital secret agent. When Chuck opens an e-mail subliminally encoded with government secrets, he unwittingly downloads an entire server of sensitive data into his brain.
I think its pretty cool.