Looks like it will work fine, no suprises really. Go here to find out how NES emulation works through Pops:
1.) Download imbNES v1.3.2.
2.) Un-zip all the files to a new directory on your hard drive.
3.) Run rombank.exe
4.) Under Add/Remove Roms, click the first button to add all the ROMs in a given folder to your ROM list.
5.) Once you've added all your ROMs, you can manipulate the list to get it just the way you want it. At the very least, you'll probably want to sort the list alphabetically using the "A-Z" button.
6.) When you're done making your ROM list, click the 'Build imbNES ISO' button in the lower left corner. Then pick the appropriate license (USA | Japan | Europe), press 'Build ISO', and choose where to save your ISO image.
7.) Once the build process if finished, you can close rombank.exe. Now you're ready to convert the CD image using POPStation...
No need for it really, but meh, its a POC.